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Table 4 Some examples of CTH of HMF to FDM

From: Recent advances in catalytic synthesis of 2,5-furandimethanol from 5-hydroxymethylfurfural and carbohydrates

Catalyst

H source

Solvent

T (oC)

t (h)

Conversion of HMF (%)

FDM yield (mol%)

Refs.

Co–NC

Formic acid

1,4-Dioxane

160

5

88.2

81.4

(Xu et al. 2021)

Co–NC

Formic acid

1,4-Dioxane

160

10

100

86

(Xu et al. 2021)

Co1.6/UiO-66-NH2

Isopropanol

Isopropanol

100

4

92.6

88.8

(Wang et al. 2022b)

Hf-DTMP

2-Butanol

2-Butanol

130

4

99.1

96.8

(Hu et al. 2019)

40 wt% CuO/Bhm

Ethanol

Ethanol

160

3

75.9

73.5

(Huang et al. 2023)

Zr/NC

Isopropanol

Isopropanol

130

2.5

100

99.6

(Hu et al. 2022)