Table 1 Comparison of cytochrome C catalyzed ATRP with recently reported representative protein catalyzed ATRP
From: Cytochrome C catalyzed oxygen tolerant atom-transfer radical polymerization
Monomer | Catalyst | Reducing agent/additive | Initiator | pH | Time (h) | Conversion (%) | Mn (g/mol) | PDI (Mw/Mn) | Aerobic/anaerobic | References |
|---|---|---|---|---|---|---|---|---|---|---|
PEGMA | LTV | VC | EBiB | 7.0 | 1.0 | 20.0 | 2.72 × 105 | 2.43 | Anaerobic | (Ng et al. 2011b) |
PEGMA | DhHP-6 | Sodium l-ascorbate | EBiB | 6.5 | 2.0 | 80.7 | 6.02 × 103 | 1.08 | Anaerobic | (Wang et al. 2018) |
PEGMA | DhHP-6@ZIF-8 | l-Ascorbate | BPN | 8.0 | 4.0 | 85.5 | 8.20 × 103 | 1.10 | Anaerobic | (Jiang et al. 2017) |
PEGA | CBL | VC | EBiB | N/A | 8.0 | 50.0 | 9.81 × 103 | 1.61 | Anaerobic | (Ng et al. 2011a) |
NIPAAm | Hematin | Sodium l-ascorbate | EBiB | N/A | 24.0 | 80.0 | 3.18 × 104 | 1.80 | Anaerobic | (Yamashita et al. 2013) |
OEOMA | Mesohemin-(MPEG550)2 | Sodium l-ascorbate | PEG2000-Bra | 7.0 | 6.0 | 60.0 | 6.30 × 104 | 1.19 | Anaerobic | (Simakova et al. 2013) |
OEOMA | Hemin | Sodium l-ascorbate | PEG2000-Bra | 7.0 | 18.0 | 50.0 | 6.00 × 104 | 1.32 | Anaerobic | (Simakova et al. 2013) |
OEOMA | HRP | Acetylacetonate | EBPA | 6.0 | 0.5 | 58.0 | 3.84 × 104 | 1.13 | Anaerobic | (Matyjaszewski et al. 2018) |
BMA | GOx | Sodium pyruvate | EBPA | N/A | 6.5 | 89.0 | 3.24 × 104 | 1.80 | Anaerobic | (Wang et al. 2018) |
NIPAAm | Hb | Sodium nitrate | BIBB | 4.0 | 16.7 | N/A | N/A | N/A | Anaerobic | (Divandari et al. 2017) |
SMA | Cyto C | VC | BIBB | 4.0 | 5 | 21.6 | 3.85 × 104 | 1.26 | Aerobic | This study |
SMA | Cyto C | VC | BIBB | 7.2 | 5 | 48.6 | 1.58 × 105 | 1.19 | Anaerobic | This study |